Complexation of trivalent lanthanide cations with amino(O-alkyl)methylenephosphonic acids as the closest organophosphorus analogues of nitrilotriacetic acid
https://doi.org/10.26907/2542-064X.2025.2.223-241
Abstract
The complexation of new complexones, analogues of nitrilotriacetic (H3NTA) and nitrilotrimethylenephosphonic (H6NTP) acids containing monobasic (O-alkyl)methylenephosphonic fragments as donor groups, with trivalent cations of lanthanides was studied. The stability and deprotonation constants of 1:1 complexes and the fractional distribution of complex forms were determined using pH-metric titration in combination with mathematical modeling. The complexation properties of N-[(O-butyl)hydroxyphosphorylmethyl]iminodiacetic acid were compared with those of H3NTA based on the linear free-energy relationships.
About the Authors
A. R. Garifzyanov
Kazan Federal University
Russian Federation
Competing Interests:
Russian Federation
Airat R. Garifzyanov - Cand. Sci. (Chemistry), Associate Professor, Department of Analytical Chemistry, A.M. Butlerov Institute of Chemistry.
Kazan
Competing Interests:
The authors declare no conflicts of interest
I. I. Mirzayanov
Kazan National Research Technological University
Russian Federation
Competing Interests:
Russian Federation
Ildar I. Mirzayanov - Cand. Sci. (Chemistry), Associate Professor, Department of Analytical Chemistry, Certification and Quality Management, Institute of Petroleum, Chemistry and Nanotechnologies.
Kazan
Competing Interests:
The authors declare no conflicts of interest
I. D. Shurygin
Kazan Federal University
Russian Federation
Competing Interests:
Russian Federation
Igor D. Shurygin - Postgraduate Student, Department of Analytical Chemistry, A.M. Butlerov Institute of Chemistry.
Kazan
Competing Interests:
The authors declare no conflicts of interest
E. O. Chibirev
Kazan Federal University
Russian Federation
Competing Interests:
Russian Federation
Egor O. Chibirev - Assistant Professor, Department of Analytical Chemistry, A.M. Butlerov Institute of Chemistry.
Kazan
Competing Interests:
The authors declare no conflicts of interest
F. V. Devyatov
Kazan Federal University
Russian Federation
Competing Interests:
Russian Federation
Fedor V. Devyatov - Dr. Sci. (Chemistry), Full Professor, Department of Inorganic Chemistry.
Kazan
Competing Interests:
The authors declare no conflicts of interest
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Garifzyanov A.R., Mirzayanov I.I., Shurygin I.D., Chibirev E.O., Devyatov F.V. Complexation of trivalent lanthanide cations with amino(O-alkyl)methylenephosphonic acids as the closest organophosphorus analogues of nitrilotriacetic acid. Uchenye Zapiski Kazanskogo Universiteta Seriya Estestvennye Nauki. 2025;167(2):223-241. (In Russ.) https://doi.org/10.26907/2542-064X.2025.2.223-241
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