uzakuescУченые записки Казанского университета. Серия Естественные наукиUchenye Zapiski Kazanskogo Universiteta Seriya Estestvennye Nauki2542-064X2500-218XKazan (Volga Region) Federal University10.26907/2542-064X.2024.2.187-209uzakuesc-115Research ArticleСтатьиМембраны на основе целлофана для очистки водных сред от загрязнений различной природыCellophane-Based Membranes for Purification of Aqueous Media from Various PollutantsЮшкинА. А.YushkinA. A.

Юшкин Алексей Александрович, кандидат химических наук, старший научный сотрудник лаборатории полимерных мембран 

Ленинский просп., д. 29, ГСП-1, г. Москва, 119991 

Moscow, 119991 

Halex@ips.ac.ruНебесскаяА. П.NebesskayaA. P.

Небесская Александра Павловна, младший научный сотрудник лаборатории полимерных мембран 

Ленинский просп., д. 29, ГСП-1, г. Москва, 119991 

Moscow, 119991 

nebesskaya@ips.ac.ruГрушевенкоЕ. А.GrushevenkoE. A.

Грушевенко Евгения Александровна, кандидат химических наук, старший научный сотрудник лаборатории полимерных мембран 

Ленинский просп., д. 29, ГСП-1, г. Москва, 119991

Moscow, 119991 

evgrushevenko@ips.ac.ruМалаховА. О.MalakhovA. O.

Малахов Александр Олегович, кандидат химических наук, старший научный сотрудник лаборатории полимерных мембран 

Ленинский просп., д. 29, ГСП-1, г. Москва, 119991

Moscow, 119991 

malakhov@ips.ac.ruАнохинаТ. С.AnokhinaT. S.

Анохина Татьяна Сергеевна, кандидат химических наук, и.о. заведующего лабораторией полимерных мембран 

Ленинский просп., д. 29, ГСП-1, г. Москва, 119991

Moscow, 119991 

tsanokhina@ips.ac.ruВолковА. В.VolkovA. V.

Волков Алексей Владимирович, доктор химических наук, профессор, главный научный сотрудник лаборатории полимерных мембран, советник директора 

Ленинский просп., д. 29, ГСП-1, г. Москва, 119991

Moscow, 119991 

avolkov@ips.ac.ruИнститут нефтехимического синтеза им. А.В. Топчиева Российской академии наукРоссияA.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of SciencesRussian Federation2024080720241662187209Copyright © Юшкин А.А., Небесская А.П., Грушевенко Е.А., Малахов А.О., Анохина Т.С., Волков А.В., 20242024Юшкин А.А., Небесская А.П., Грушевенко Е.А., Малахов А.О., Анохина Т.С., Волков А.В.Yushkin A.A., Nebesskaya A.P., Grushevenko E.A., Malakhov A.O., Anokhina T.S., Volkov A.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://uzakuesc.elpub.ru/jour/article/view/115

В работе исследован процесс нанофильтрационной очистки воды от органических загрязнителей различной природы. В качестве мембраны в работе использована целлофановая пленка – материал на основе дешевого природного сырья. В качестве модельных веществ, от которых очищали воду, рассмотрены красители сафранин О, оранжевый II и ремазол бриллиантовый синий Р, характеризующиеся различной молекулярной массой, химическим составом и зарядом, а также антибиотик цефтриаксон. Показано, что проницаемость целлофана по воде составляет 0.145 ± 0.017 кг/(м2∙ч∙атм). При этом мембраны из целлофана хорошо задерживают из водных сред растворенные органические вещества анионного типа, содержащие кислотные группы. При выделении из воды анионных красителей оранжевый II и ремазол бриллиантовый синий Р коэффициенты задержания составили 97 ± 2 и 99 ± 1% соответственно. В случае катионного красителя сафранин О наблюдали отрицательные значения коэффициентов задержания на уровне –7 ± 3%. В то же время, для антибиотика цефтриаксона коэффициент задержания составил всего 41 ± 5%, что обусловлено его высоким сродством к целлофану и стерическими ограничениями.

The process of nanofiltration purification of water from various organic pollutants was examined. Cellophane film made from cheap natural raw materials was used as a membrane. The model substances targeted for removal were dyes (Safranin O, Orange II, and Remazol Brilliant Blue R, each differing in molecular weight, chemical composition, and charge) and ceftriaxone. The obtained cellophane permeability to water was 0.145 kg/(m2∙h∙atm). Cellophane membranes were found to be effective in retaining dissolved anionic substances containing acid groups. When Orange II and Remazol Brilliant Blue R were removed from the water, the retention coefficients were 97 ± 2 and 99 ± 1%, respectively. For the cationic dye Safranin O, the retention coefficient values were negative, –7 ± 3%. At the same time, ceftriaxone had the retention coefficient of only 41 ± 5%, which can be attributed to a combination of factors, such as its high affinity for cellophane and steric restrictions.

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The authors declare that there are no conflicts of interest present.